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in Chemical Bonding by (45.9k points)
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Linear form of carbon dioxide molecule has two polar bonds. yet the molecule has zero dipole moment, why?

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1. The linear form of carbon dioxide has zero dipole moment, even though it has two polar bonds.

2. In CO2 , there are two polar bonds [C = O], which have dipole moments that are equal in magnitude but have opposite direction.

3. Hence the net dipole moment of the CO2 is µ = µ1 + µ2 = µ1 +( – µ1 ) = 0

4

5. In this case

µ = \(\overset{\rightarrow}{\mu_1}\) + \(\overset{\rightarrow}{\mu_2}\) = \(\overset{\rightarrow}{\mu_1}\) + \((-\bar{\mu_1})\) = 0

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