1. Naphthalene, camphor and benzoic acid when heated, pass directly from solid to vapour without melting. On cooling the vapours will give back solid. This phenomenon is known as sublimation. This technique is used to purify naphthalene, camphor from non volatile impurities.
2. Substances to he purified is taken in a beaker. It is covered with a watch glass. The beaker is heated for a while and the resulting vapours condense on the bottom of the watch glass. Then the watch glass is removed and the crystals are collected.