When a big drop having radius R breaks into N droplets each of radius r, the volume remains constant.
∴ Volume of big drop = N × volume of each small drop
\(\frac{4}{3}πR^3\) = N × \(\frac{4}{3}πr_3\)
Or R3 = Nr3 or N = \(\frac{R^3}{r^3}\)
Change in surface area = 4\(πR^3\)− N4\(πr^2\)
= 4π(R2 − Nr2)
Energy released = T × ∆A
= T × 4π(R2 − Nr2)
Released energy lowers the temperature by ∆θ, then
Energy released = ms∆θ
T × 4π(R2 − Nr2) = \((\frac{4}{3} × R^3 × ρ)\)s∆θ
\([^{s\, =\,\text {specific heat of liquid}}_{ρ\, =\, \text {density}}]\)
or ∆θ = \(\frac{T×4π(R^2−Nr^2)}{\frac{4}{3}πR^3ρ×s}\) = \(\frac{3T}{ρS} [\frac{R^2}{R^3} − \frac{Nr^2}{R^3}]\)
∆θ = \(\frac{3T}{ρS} [\frac{1}{R} − \frac{1}{r}]\)
∵ (N = \(\frac{R^3}{r^3}\))