(i) Propanal and propanone :- Propanal and propanone can be distinguished by their reactions with Tollens’ reagent.
Propanal will form the silver mirror, but propanone does not react.
(ii) Benzaldehyde and acetophenone :- Benzaldehyde and acetophenone can be distinguished by Tollens’ test.
Benzaldehyde will form silver mirror, on treatment with Tollens’ reagent whereas acetophenone will not show Tollens’ Test.