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Illustrate the following name reactions giving a chemical equations in each case :

(i) Clemmensen reaction 

(ii) Cannizzaro’s reaction

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(i) Clemmensen reduction :- The carbonyl group of aldehydes and ketones is reduced to CH2 group on treatment with zinc amalgam and concentrated hydrochloric acid.

(ii) Cannizzaro’s reaction :- Aldehydes which do not contain α-H atom undergo disproportionation when heated with concentrated (50%) NaOH.

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