Diagram according to the given question is,
Now, direction of electric field at the center of the square is as given below.
Electric field due to A and Electric field due to C are in opposite direction and same in magnitude( due to same charges present at A and C and corners have same distance from the center ) so it cancels each other.
Similarly, Electric field due to B and Electric field due to D are in opposite direction and same in magnitude( due to same charges present at B and D and corners have same distance from the center ) so it cancels each other.
So, net electric field at center of the square is zero.
I HOPW YOU WILL UNDERSTAND.