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Consider the following compounds : [Co (NH3)5 NO2] Cl2 and [Co (NH3)5ONO] Cl2

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Consider the following compounds :

[Co (NH3)5 NO2] Cl2 and [Co (NH3)5ONO] Cl2

1. Identify the isomerism exhibited by these compounds.

2. Explain ionisation isomerism with example.

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1. Linkage isomerism

2. This form of isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion.

e.g. [Co(NH3)5Cl] SO4 & [Co(NH3)5SO4]Cl

These complexes ionises as :

  • [Co(NH3)5Cl] SO4 → [Co(NH3)5Cl]2+ + SO42-
  • [Co(NH3)5SO4] Cl → [Co(NH3)5SO4] + Cl- 
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