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In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. 

(i) Both assertion and reason are correct and the reason is correct explanation of assertion. 

(ii) Both assertion and reason are correct but reason does not explain assertion. 

(iii) Assertion is correct but reason is incorrect. 

(iv) Both assertion and reason are incorrect. 

(v) Assertion is incorrect but reason is correct.

Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.

Reason:Reactant molecules undergo chemical change irrespective of their orientation during collision.

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(iii) Assertion is correct but reason is incorrect. 

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