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+2 votes
16.9k views
in Chemistry by (29.3k points)

A KCl solution of conductivity 0.14 S m–1 shows a resistance of 4.19 W in a conductivity cell. If the same cell is filled with an HCl solution, the resistance drops to 1.03 W. The conductivity of the HCl solution is ...... x 10–2 S m–1. (Round off to the Nearest Integer).

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1 Answer

+4 votes
by (30.3k points)

k = \(\frac{1}{R}.G*\)

For same conductivity cell, G* is constant and hence k.R. = constant.

∴ 0.14 × 4.19 = k × 1.03

or, k of HCl solution = \(\frac{0.14\times4.19}{1.03}\)

= 0.5695 Sm–1 

= 56.95 × 10–2 Sm–1

= 57 × 10–2 Sm–1

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