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Which among the following sets of quantum numbers is/are not possible?

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Which among the following sets of quantum numbers is/are not possible? 

a) n = 3, l = 2, m = 0, s = +½ 

b) n = 2, l= 1, m = 0, s = +½ 

c) n = 1, l= 0, m = 0, s = -½

d) n = 4, l = 2, m = 2, s = -½

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All sets are possible.

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