1. For n = 4, l can have values 0, 1, 2, 3. Thus, there are four sub-shells in n = 4 energy level.
These four sub-shells are 4s, 4p, 4d and 4f.
2. For n = 4, the number of orbitals = (4)2 = 16.
Each orbital can have one electron with ms = –\(\frac{1}{2}\) .
Thus, there are 16 electrons in sub-shells having n = 4 and ms = -\(\frac{1}{2}\)