Oxides of Sulphur and Nitrogen, mist of HCI and Phosphoric acid, etc. present in polluted air dissolve in rain water making it more acidic. This is known as acidic rain. SO2 and NO2 present in polluted air are the major contributors of acid rain.
2SO2 (g) + O2(g) +2H2O(l) → 2H2SO4 (aq)
4NO2 (g) + O2(g) + 2H2O(l) → 2HNO3(aq)