Answer :
1. Answer: (d) system can do work
Explanation: According to First law of thermodynamics,dQ = dU + dW a system can do work and increase it's internal energy provided we supply heat.
2. Answer: (a) may be in thermal equilibrium
Explanation: By zeroth law of thermodynamics, there are three parts to the system. Let's say x,y,z.It is given that in the question is, A system Y is neither in thermal equilibrium with Y nor with Z. But, their is possibility by Zeroth law of theromodynamics that Y and Z may be in thermol eqyuilibrium.
3. Answer: (d) All of the above
Explanation: Macroscopic variable is a measurable quantity used to describe the complete state of the system. The state of a macroscopic system in equilibrium can be described in terms of measurable properties as temperature, pressure, and volume, which are also known as thermodynamic variables.
4. Answer: (a) Internal energy
Explanation: State function is a proterty of a system that depends only on its present state, which is completely determined by variables such as temperature and pressure. Thus. Internal energy and volume are state function. On the other hand, heat and work are not state functions becasue they are not properties of a system
5. Answer: (a) temperature
Explanation: The internal energy and enthalpy of ideal gases depends only on temperature, not on volume or pressure.
6. Answer: (a) pressure, volume and temperature
Explanation: The state of a system is defined by ascribing values to a sufficient number of variables. In mechanics, the state of a body is specified by means of a few measurable quantities, such as the position of centre of mass, its velocity and acceleration etc. In thermodynamics, however we disregard these mechanical coordinates and instead consider the interior of the system, find out directly or indirectly by experiments same measurable quantities upon which the internal state of the system for all thermodynamic purposes, the state of a system can be represented by specifying its pressure p, volume V and the temperature T provided the system is in equilibrium.
7. Answer: (a) Work
Explanation: Work does not characterized the thermodynamic state of matter, it is a path function giving only relationship between two quantities.
8. Answer: (b) increase with increase in temperature
Explanation: The internal energy of a substance always increases with increase in temperature.
9. Answer: (a) temperature
Explanation: Zeroth law defines temperature and first law defines internal energy.
10. Answer: (a) isothermal expansion
Explanation: The Carnot cycle consists of the following four processes: A reversible isothermal gas expansion process. In this process, the ideal gas in the system absorbs qin amount heat from a heat source at a high temperature Thigh, expands and does work on surroundings.
11. Answer: (a) second law of thermodynamics
Explanation: From Kelvin Plank statement and Claussius's statement we can say that heat can not be flow form lower temperature to higher temperature until and unless we are adding any external source like heat pump, which justifies second law of thermodynamics.
12. Answer: (a) refrigerator
Explanation: An air conditioner works using a thermodynamic cycle called the refrigeration cycle. It does this by changing the pressure and state of the refrigerant to absorb or release heat. The refrigerant (aka coolant) absorbs heat from inside of your home and then pumps it outside.
13. Answer: (a) Isothermal compression
Explanation: Isothermal compression is reversible, for example, Carnot cycle, heat engine.
14. Answer: (a) All reversible cycles have same efficiency
Explanation: We know that carnot cycle is reversible cycle, and reversible cycle has maximum efficiency of all other cycles.
15. Answer: (a) heat engine working in backward direction
Explanation: As we know, a heat engine is something that converts heat into mechanical work.
Usually, a refrigerator is a device that is used to cool things.But according to the second law of thermodynamics, a refrigerator is a device which is used to turn mechanical work into heat. Therefore, we can say that a refrigerator is a heat engine that works in a backward direction.
16. Answer: (a) adiabatic
Explanation: The entire system is completely insulated and the free expansion of the gas will take place, the temperature of the gas will remain constant. So the process will be adiabatic.
17. Answer: (b) the temperatures of the source and sink
Explanation: \(\eta=1-\frac{T_2}{T_1}\)
It depends on the temperature of source and sink.
18. Answer: (a) compressing the gas through adiabatic process will require more work to be done
Explanation: Wext = negative of area with volume-axis
W(adiabatic) > W(isothermal)
19. Answer: (a) ΔU = −ΔW, in a adiabatic process
Explanation: ΔQ = ΔU + W
For an adiabatic process, ΔQ = 0.
∴ΔU = −W
20. Answer: (a) In an isochoric process pressure remains constant
Explanation: Isochoric → Volume constant
21. Answer: (c) E=0
Explanation: Internal energy depends only on the initial and final states of temperature and not on the path. In a cyclic process, as initial and final states are the same, the internal energy change is zero. Hence E is ΔU, the internal energy change.
22. Answer: (c) Second
Explanation: A sink, that is the system where heat is rejected, is essential for the conversion of heat into work. Otherwise, change in entropy of the universe won't be positive.Which is must according to the second law of thermodynamics.
23. Answer: (d) R
Explanation: R is a constant and is not a thermodynamic constant.
24. Answer: (b) compressibility only
Explanation: In isothermal expansion, the temperature remains constant over the process.Thus, the pressure is only variable dependent on the volume or the compressibility of the system.
25. Answer: (a) Infinite
Explanation: In isothermal process temperature remains constant. i.e.
ΔT=0. Hence according to \(C=\frac{Q}{m\Delta T}\) ⇒Ciso = ∞
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