Answer:
1. Answer: (d) 26.7
Explanation: Atomic weight = (Equivalent weight \(\times\) Valency)
=(8.9 \(\times\) 3)
= 26.7
2. Answer : (d) 3.0 N
Explanation: H3PO4 is tribasic
So N = 3M
= 3 \(\times\) 1 = 3
3. Answer : (c) Three Mole
Explanation: Molecular weight of CaCl2 = 111g/mol
Ions in one calcium chloride molecule = Ca+2 + 2Cl- = 3 ions
4. Answer : (b) 20 ml
Explanation: NH3 + HCl→ NH4Cl
According to the given question, 1 ml NH3 reacts with 1 ml HCl to produce 1 ml of NH4Cl.So, 20 ml of ammonia reacts with 20 ml of HCl to produce 20 ml of resultant NH4Cl. The rest of HCl will stay unreacted.
5. Answer : (c) Pb2+
Explanation: Atom in highest oxidation state can oxidize iodide to liberate I2 which is volumetrically measured by iodometric titration using hypo.
2I–→I2
Pb+2 → Lowest oxidation state cannot oxidise iodide to I2
6. Answer : (b) 5
Explanation: Exponential form of 3400 = 3.4 \(\times\) 103
∵ All non-zero digits are significant numbers.
∴ 3400 has 2 significant numbers
7. Answer : (c) Atomicity
Explanation: Symbol of an element represents the name along with the number of same atoms in room condition, which is its atomicity, of that element.
8. Answer : (a) Kelvin
Explanation: The kelvin is the SI unit of thermodynamic temperature, and one of the seven SI base units. Unusually in the SI, we also define another unit of temperature, called the degree Celsius (°C).
9. Answer : (a) sublimation
Explanation: Sublimation separates a mixture of solids, one of which changes directly from a solid to vapour on heating without going through the liquid state. This change is called sublimation.
10. Answer : (a) Candle
Explanation: The type of mixture in which the constituent elements are different and are not uniformly distributed, it is called heterogeneous substance.
11. Answer : (a) Sucrose solution
Explanation: Sugar solution is a mixture and made up of different kinds of molecules. So it is not a pure substance.
12. Answer : (a) eV and L-atm
Explanation: Smallest and largest amount of energy respectively eV and L-atm.
1eV = 1.6 \(\times\) 10−19J
1L−amt = 101.325J
13. Answer : (a) 3,3 and 3 respectively
Explanation: (i) All non-zero digits are significant.
(ii) Non-zero digits to the right of the decimal point are significant.
(iii) Zeroes to the left of the first non-zero digit in a number are not significant.
14. Answer : (a) gravity separation
Explanation: In gravity separation difference in density of particles is employed In molecular attraction, mainly exchange of cations to anions among given two molecules.
15. Answer : (c) A compound cannot be separated into its constituent elements by physical methods of separation
Explanation: A compound is a pure substance containing two or more than two elements combined together in a fixed proportion by mass and which can be decomposed into its constituent elements by suitable chemical methods. Further, the properties of a compound are quite different from the properties of constituent elements.
16. Answer : (d) Dulong Petit's law
Explanation: According to Dulong Petit's law, the product of atomic mass and specific heat of any element is constant and it is equals to 6.4.
17. Answer : (a) 16g of O2 and 14g of N2
Explanation: 16g O2 has number of moles = 16/32 = 1/2
14g N2 has number of moles = 14/28 = 1/2
Hence, no of moles are same. So number of molecules are also same.
18. Answer : (a) 6.87
Explanation: 1 mole CCl4 vapours = 12 + 4 \(\times\) 35.5 = 154g
At STP, volume of 1 mole of a gas = 22.4 L
Thus, 154g = 22.4L
∴ Density of CCl4 vapours =154/22.4 gL−1
= 6.87gL−1
19. Answer : (d) 36 g
Explanation: 1 mole of K4[Fe(CN)6] contain carbon = 6 g atoms
0.5 mole of K4[Fe(CN)6] contain carbon = 3g atoms
Mass of carbon in grams \(=(12g)\times\frac{(3\;g\;atoms)}{(1g\;atom)}\)
= 36 g
20. Answer : (a) 0.5
Explanation: 3 moles of oxygen is that in 1 mole of BaCO3
∴1.5 moles of oxygen is that in mole of BaCO3
\(=\frac{1}{3}\times1.5=\frac{1}{2}\)
= 0.5
21. Answer :(a) C2H4
Explanation: Mass of 1 L of gas = mass of 1 L of N2 according to Avogadro’s hypothesis.
Molecular masses will also be equal, then molecular mass of the gas=28. Hence formula is C2H4 (2 ×12 + 4 × 1 = 28).
22. Answer : (c) Kg/m2
Explanation: Pressure is force per unit area so Kg/m2 cannot be a unit of pressure.
23. Answer : (a) 10–13 cm
Explanation: A Fermi is equivalent to a femtometre, and it is the older non–SI measurement unit of length, It is named in honour of Italian physicist Enrico Fermi. 1Fm = 10– 15m = 10–13 cm.
24. Answer : (a) Law of multiple proportions
Explanation: According to the law of multiple proportions, when two elements combine with each other to form two or more than two compounds, the masses of one of the elements which combine with a fixed mass of the other, bear a simple whole number ratio.
25. Answer : (a) Molarity
Explanation: Molarity and normality are temperature dependent because they involve volume of solutions. Volume is dependent on temperature. Molality, mole fraction and weight percentage does not depend on temperature because they involve masses of solute and solvent.
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