The Sun and surrounding sky appear red at sunrise and at sunset because at this time the Sun is near the horizon and sunlight has to travel the greatest distance through the atmosphere to reach us. Thus most of the blue colour present in sunlight has been scattered out and away from our line of sight, leaving behind mainly red colour in the direct sunlight beam that reaches our eyes.
When the Sun is overhead (as at noon) then the light coming from the Sun has to travel a relatively shorter distance through the atmosphere to reach us. Thus only a little of blue colour of the white light is scattered. Since the light coming from the overhead Sun has almost all its component colours in the right proportion, therefore the Sun in the sky overhead appears white.
