Cycloalkenes and alka- dienes are structural isomers and it is observed that the isomerisation reaction of cyclo-butene into 1,3, buta-diene follows 1st order kinetics with respect to cyclobutene. The rate constant of the reaction can be determined by hydrogenting ( reaction with `H_(2)` to remove unsaturation) the reaction mixture and different instant and measuring the amount of hydrogen required. In one such experiment two separate glass flasks of volume 1 litres. were added with same amount of cyclobutene and sealed. While one flask was broken after 138.6 min and the contents required 39.2 ml of `H_(2)` gas at 1 atm pressure and 273K, where as other flask was broken after a very long time and the contents required 44.8 ml of `H_(2)` gas at 1 tam pressure and 273K . From the information given above and given data, anwer the questions that follows:
`Delta H_(f)^(@)` Cyclobutene=175kJ/mol
`DeltaH_(f)^(@)`Buta-1,3-diene =125kJ/mol
which of the followin cannot be a possible value of volume of hydrogen measured at 1 atm and 300K required if the first bottle is broken at any other tim?
A. 20ml
B. 25ml
C. 29ml
D. 40ml
