Nuclear charge experienced by an electron (present in a multi-electron atom) is dependant upon the distance between the nucleus and the orbital, in which the electron is present. As the distance increases, the effective nuclear charge also decreases.
Among p-orbitals, 4p orbitals are farthest from the nucleus of bromine atom with (+35) charge. Hence, the electrons in the 4p orbital will experience the lowest effective nuclear charge. These electrons are shielded by electrons present in the 2p and 3p orbitals along with the s-orbitals. Therefore, they will experience the lowest nuclear charge.
