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Write the increasing order of energies of 4s,3p,4p and 3d.

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For 4s,n=4,l=0,(n+l)=4
For 3p,n=3,l=1,(n+l)=4
For 4p,n=4,l=1,(n+l)=5
For 3d,n=3,l=2,(n+l)=5
`rArr 3plt4slt3dlt4p` increasing order

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