Answer is : (c) sublimation
A mixture of NH4Cl and NaCl can be separated by the process of sublimation. In this process, solid directly changes to gaseous state without passing into liquid state. NH4Cl sublimes to gaseous NH3 and HCl upon heating whereas NaCl does not sublime, the reaction can be written as
NH4Cl(s) → NH3(g) + HCl(g)