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The energy required to break one mole of Cl–Cl bonds in Cl2 is 242 kJ mol–1. The longest wavelength of light capable of breaking a single Cl – Cl bond is (c = 3 x 108 ms–1 and NA = 6.02 x 1023 mol–1)

(1) 594 nm 

(2) 640 nm 

(3) 700 nm 

(4) 494 nm

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Energy required for 1 Cl2 molecule = (242x103)/NA) (242x103) Joules.

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