Weight of balloon = 100 kg = 100 x 103 g = 105 g
Volume of balloon
Weight of the gas filled in balloon = PVm/RT = 1.66 x 4190 x 103 x 4/ 0.083 x 300
= 1.117 x 106 g
Total weight of (gas + balloon) = 11.17 x 105 + 105 = 12.17 x 105 g
Weight of air displaced (Volume x density) by balloon
= 1.2 x 4190 x 106/103 = 5.028 x 106 g
Pay load =50.25 x 105 - 12.17 x 105 = 38.11 x 105 g
= 3811 kg