Yes, they do. Scooters and motor cycles are more dominant source of air pollution as they emit soot and organic particles. In urban areas this proportion is high. These particles are toxic and they create heavy air pollution.
The two-wheelers have two-stroke engines. Such engines are far less efficient in burning the fuel that is used in the vehicles. The exhaust systems are also less effective at removing pollutants. On the contrary most of the four-wheelers have catalytic converters. Therefore, the exhaust fumes from scooters contain higher levels of the chemicals found in the fuel and oil they use.
The vehicles with two-stroke engine such as two wheelers emit significantly more primary organic aerosols and volatile organic compounds from incomplete burning of the fuel. They also produce significant secondary organic aerosols as gases released from the exhaust react with the air and microscopic particles of soot.
These pollutants increase the risk of heart and lung disease. Older two-stroke vehicles produced reactive oxygen molecules that are known to be potentially harmful for lung health. In recent times there is excessive use of two-wheelers which is deteriorating the air quality to great extent.