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in Atomic structure by (15 points)
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Derive Schrodinger time dependent wave equation

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Considering a complex plane wave:

Ψ (x, t) = Aei(kx - ωt).

Now the Hamiltonian of a system is

H = T + V

Where ‘V’ is the potential energy and ‘T’ is the kinetic energy. As we already know that ‘H’ is the total energy, we can rewrite the equation as:

E = p2/2m + V(x)

Now taking the derivatives,

We know that,

p = 2πh/λ and k = 2π/λ

where ‘λ’ is the wavelength and ‘k’ is the wave number.

We have

k = p/h

Therefore,

Now multiplying Ψ (x, t) to the Hamiltonian we get,

The above expression can be written as:

We already know that the energy wave of a matter wave is written as

E = hω,

So we can say that

Now combining the right parts, we can get the Schrodinger Wave Equation.

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