(i) Impurities are more Soluble in the molten state than in the solid state of the metal.
Example: Ge/Si/B (any other)
(ii) (a) Zn/Hg
(b) Sn
Detailed Answer:
(i) Zone refining is based on the principle that the impurities are more soluble in the melt than in the solid state of the metal. Silicon, boron etc. are refined by this method.