i. Molecular formula of both (a) and (b) are same i.e., C3H6O.
ii. Compound (a), has a ketone (-CO-) functional group (i.e., acetone) and compound.
(b) has an aldehyde (-CHO) functional group (i.e., propionaldehyde). Both the compounds have different functional groups.
iii. Compound (a) and (b) are isomers of each other.
[Note : Aldehydes and ketones are the functional group isomers of each other.]