(i) It reacts with chlorine within the presence of charcoal as an impetus to give sulphuryl chloride (SO2Cl2) .
SO2 + Cl2 → SO2Cl2
Sulphur dioxide Chlorine (Catalyst) Sulphuryl Chloride
(ii) Within the sight of vanadium penta oxide ( catalyst) , it gives sulphur trioxide. V2O5
SO2 + O2 → SO3
Sulphur dioxide Oxygen Sulphur trioxide