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Arrange the compounds in increasing order of their boiling pts.

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Arrange the compounds in increasing order of their boiling pts.

(a) CH3CH2CH2CH2Br, CH3CH2CHBrCH3,(CH3)3C Br

(b) CH3Br, CH2Br2, CHBr3

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(a) (CH3)3C-Br< CH3CH2CHBrCH3< CH3CH2CH2CH2Br Boiling point decreasing on increasing the branching

(b) CH3Br< CH2Br2< CHBr3 Boiling point increases due increasing molecular mass.

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