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How are 0.50 mol Na2CO3and 0.50 M Na2CO3 different?

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Molar mass of Na2CO3 = (2×23)+12.00+(3×16) = 106 g mol-1 

∴0.50 mol Na2CO3 means 0.50×106g = 53g 0.50 M Na2CO3 means 

0.50 mol of Na2CO3 i.e. 53g of Na2CO3 are present in 1litre of the solution.

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