The actual expression for calculating the value of α is, Ka = Cα2/1-α If we make the assumption that α is very small compared to one and ignore it in the denominator, we get, Ka = Cα2 . By ignoring the α in the denominator, we increase the value of the denominator. This will consequently increase the value of the numerator (since the ratio is a constant) consequently the value of α calculated after the assumption will be greater than the actual value of α . If this value of α is less than or equal to 0.1 then it means that the actual value of α will be much less compared to 0.1. Therefore the assumption is valid. If this value of α is greater than 0.1, than the actual value of α may be greater, equal to or less than 0.1. So here we cannot predict and so we do not make the assumption.