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 An aqueous solution of metal bromide MBr2 (0.05M) in saturated with H2S. What is the minimum pH at which MS will ppt.? 

Ksp =(MS) = 6 x 10–21

Concentration of standard H2S = 1 

Ka1(H2S) = 1 x 10–7

Ka2(H2S) = 1.3 x 10–13

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In saturated solution of MS 

The precipitate of MS will form only if [S] exceeds the concentration of 

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