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Hall-Heroult’s process is given by
1. \(ZnO+C\xrightarrow[]{coke,1673K}Zn+CO\)
2. Cr2O3 + 2Al ⟶ Al2O3 + 2Cr
3. 2Al2O3 + 3C ⟶ 4Al + 3CO2
4. Cu2+ (aq) + H2 (g) ⟶ Cu (s) + 2H+ (aq)

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Correct Answer - Option 3 : 2Al2O3 + 3C ⟶ 4Al + 3CO2

Concept:

Hall-Heroult’s process is an electro-reduction process by which pure alumina (Al2O3) is reduced to crude Al.

In this process, electrolysis of a fused mixture of Al2O3, Na3 [AlF6] (cryolite) and CaF2 (fluorspar) is carried out at carbon cathode and graphite anode.

The overall reaction is represented as:

 2Al2O3 + 3C ⟶ 4Al + 3CO2

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