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One kg of air (R = 287 J/kg.K) undergoes an irreversible process between equilibrium state 1 (20° C, 0.9m3) and equilibrium state 2 (20°C, 0.6 m3). The change in entropy s2 – s1 (in J/kg.K) is _________

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Concept:

From T-dS relation,

\(Tds=dh-vdp\)

\(Tds=C_p dT-vdp\)

for an isothermal process,

\({s_2} - {s_1} = R\ln \frac{{{V_2}}}{{{V_1}}}\)\( = R\ln \frac{{{P_1}}}{{{P_2}}}\)

Calculation:

Given, T= 20o C = 293 K, V1 = 0.9 m3

T2 =  20o C = 293 K, V2 = 0.6 m3

\({s_2} - {s_1} = R\ln \frac{{{V_2}}}{{{V_1}}}\)

\(s_2 -s_1 = 287\ln \frac{{0.6}}{{0.9}} \)

\(s_2 -s_1 = -116.368 \) J/kg-K

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