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Which of the following represents an isochoric and isobaric processes respectively? (C is a constant)
1. \(\frac{P}{T} = C\) ; \(\frac{V}{T} = C\)
2. PT = C ; PV = C
3. \(\frac{P}{V} = C\) ; \(\frac{V}{P} = C\)
4. PV = C ; VT = C

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Correct Answer - Option 1 : \(\frac{P}{T} = C\) ; \(\frac{V}{T} = C\)

The correct answer is option 1) i.e. \(\frac{P}{T} = C\) ; \(\frac{V}{T} = C\)

CONCEPT:

The equation for the thermodynamic state of a gas is given by:

PV = nRT

Where P is the pressure, V is the volume, T is the temperature, n is the number of moles of the gas and R is the universal gas constant (8.314 J mol-1 K-1)

  • Isochoric process: It is a thermodynamic process where the volume of the system undergoes no change i.e. remains constant.
  • Isobaric process: It is a thermodynamic process where the pressure of the system undergoes no change i.e. remains constant.

EXPLANATION:

In a given thermodynamic system, the number of moles (n) and universal gas constant (R) remains constant in the equation of thermodynamic state.

Therefore, PV = CT

Where C represents a constant value.

For an isochoric process, volume V is constant. ⇒ PV = nRT ⇒\(\frac{P}{T} = \frac{C}{V} = C\)

For an isobaric process, pressure P is constant. ⇒ PV = nRT ⇒\(\frac{V}{T} = \frac{C}{P} = C\)

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