3 volume of hydrogen produces 2 volume of ammonia
67.2 litres of hydrogen produces = 2/3 x 67.2 = 44.8 litres
3 volume of hydrogen reacts with 1 volumes of nitrogen
67.2 litres of hydrogen reacts with = 1/3 x 67.2 = 22.4 litres
Nitrogen lefts = 44.8 - 22.4 = 22.4 litres