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Explain; why o-hydroxy benzaldehyde is a liquid at room temperature while p-hydroxy benzaldehyde is a high melting solid ?

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o-hydroxy benzaldehyde has higher intramolecular H-bonding than p-hydroxy benzaldehyde while the p-isomer has higher intermolecular H-bonding than o-hydroxy benzaldehyde.

Intermolecular H-bonding is stronger than intramolecular H-bonding. So, p-isomer is solid and have higher melting point while o-isomer is liquid.

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