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Which of the following is the correct method for synthesising methyl-t-butyl ether and why?

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Which of the following is the correct method for synthesising methyl-t-butyl ether and why?

(i)  (CH3)3 CBr + NaOMe →

(ii)  CH3Br + NaO -t-Bu →

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In these two methods, method (ii) is the correct method for the formation of ether because in method (i), alkene is formed in place of ether.

This reaction is called as Williamson's synthesis and it is based upon SN 2 reaction mechanism.

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