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At constant temperature, in a closed vessel, an ideal solution is formed by liquid – A and liquid – B; and mole-fraction of A and B are 0.6 and 0.4 respectively. If vapour pressure of pure liquids are 125.0 and 62.5 mm respectively, then their mole-fraction in vapour state are respectively – (In vessel, no other component is in gaseous form)

(a)  0.6 and 0.4

(b)  0.4 and 0.6

(c)  0.25 and 0.75

(d)  0.75 and 0.25

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correct option (d) 0.75 and 0.25

Explanation:

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