Let the charge of atomic nucleus be Ze (for hydrogen z = 1). When the electron is moving in an orbit of radius rn , the centripetal force maintaining it in this orbit is coulomb electrostatic force
Multiplyaing both sides of this equation by r\(^2_n\).
Squarring Bohr’s condition of Ist postutate we have
Comparing above two equations we have
To calculate the energy of the electron in nth permitted orbit we notice that this energy will comprise the potential as well kinetic energy of the electron.
Hence the energy of the electron in the nth orbit is
Using Bohr’s second postulate we can write
Putting the value of constants we get the value of R as 1.099 x 107 m-1
The experimental determined value of R from spectroscopic measurement is 1.097 x 107 which remarkably well agrees with the value of R obtained on the basis of Bohr’s posulates.