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A diatomic molecules has a moment of inertia I. By Bohr’s quantisation condition, its rotational energy in the nth level (n ≠ 0) is

(1) \(\frac{h^2}{8\pi ^2 In^2}\)

(2) \(\frac{h^2}{8\pi ^2 In}\)

(3) \(\frac{nh^2}{8\pi ^2 I}\)

(4) \(\frac{n^2h^2}{8\pi ^2 I}\)

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 (4) \(\frac{n^2h^2}{8\pi ^2 I}\)

Let ωn be the angular speed of molecule in nth allowed state. Its angular momentum is Ln = Iωn

From Bohr’s postulate, we have

The rotational energy of the molecule

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