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For the first row transition metals the Eo values are: Explain the irregularity in the above values.

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For the first row transition metals the Eo values are:

Explain the irregularity in the above values.

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The E0(M2+/M) values are not regular which can be explained from the irregular variation of ionisation enthalpies (Δ i H 1 + Δ i H2) and also the sublimation enthalpies which are relatively much less for manganese and vanadium.

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