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FeSO4 solution mixed with (NH4)2SO4 solution in 1 : 1 molar ratio gives the test of Fe^2+ ion but

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FeSO4 solution mixed with (NH4)2SO4 solution in 1 : 1 molar ratio gives the test of Fe2+ ion but CuSO4 solution mixed with aqueous ammonia in 1 : 4 molar ratio does not give the test of Cu2+ ion. Explain why ?

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In the first case a double salt is formed but in the second case a co-ordination compound is formed.

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