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How is KMnO4 obtained from Pyrolusite? 

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Pyrolusite with KOH and air. This produces a green colored mass, i.e, Potassium manganate . 

2KOH + MnO2 + ½ O2 → K2MnO4 + H2

Manganate ion disproportionate in neutral or acidic medium to give pink coloured Permanganate.(KMnO4

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