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How would you distinguish between butyne – 1 and butyne – 2?

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Butyne – 1 (CH3CH2C ≡ CH), having an acetylene hydrogen atom will give white precipitate with ammonical silver nitrate and red precipitate with ammonical cuprous chloride. On the other hand, butyne – 2 (CH3C ≡ C CH3) having no acetylene hydrogen atom does not respond to either of the two reagent.

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