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Explain the following observations: 

(i) Aniline dissolves in aqueous HCl. 

(ii) The amino group in ethylamine is basic whereas that in acetamide it is not basic. 

(iii) Dimethylamine is a stronger base than trimethylamine. 

(iv) Sulphanilic acid although has acidic as well as basic group, it is soluble in alkali but insoluble in mineral acids.

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Ethylamine is basic due of the presence of localised lone pair. 

Acetamide is acidic due to the presence of acidic hydrogen

More steric hinderance in Trimethylamine

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