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Which radical of group IVth gives bluish white ppt with K4 [Fe(CN)6 ] (excess)

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Which radical of group IVth gives bluish white ppt with K4 [Fe(CN)6 ] (excess).

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2 Zn(CH3COO)2 + K4[Fe)CN)6] → Zn2[Fe(CN)6] ↓ (White) + 4CH3COOK 

3 Zn2[Fe(CN)6] + K4[Fe(CN)6] → 2 Zn3K2[Fe(CN)6]2 ↓ (bluish white)

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