Let ε be emf and r the internal resistance of each cell. The equation of terminal potential difference
V = εeff - i rint becomes
V = 3ε - i rint .......(1)
where rint is effective (total) internal resistance.
From fig., when i = 0, V = 6 x 0V
∴ From (1),
6 = 3ε - 0 => ε = 6/3 =2V
i.e., emf of each cell, e = 2V