Rechargeable batteries allow for multiple usages from a cell, reducing waste and generally providing a better long-term investment in terms of dollars spent for usable device time. This is true even factoring in the higher purchase price of rechargeables and the requirement for a charger.
A rechargeable battery is generally a more sensible and sustainable replacement to one-time use batteries, which generate current through a chemical reaction in which a reactive anode is consumed. The anode in a rechargeable battery gets consumed as well but at a slower rate, allowing for many charges and discharges.
In use, rechargeable batteries are the same as conventional ones. However, after discharge the batteries are placed in a charger or, in the case of built-in batteries, an AC/DC adapter is connected.