For the first ball
OC = vx = 1 ms-1,
OE = vy = √3 ms-1
Resultant of vx and vy is given by OA
OA = √(vx2 + vy2) = √(1 + 3) = 2 ms-1
Let the resultant makes an angle α with x-axis
Resultant of v'x and v'y is given by OB
Let the resultant makes an angle α' with x-axis.
Thus, tan α' = BD/OD = 2/2 = 1 or, α' = 45°
The angle between the paths of two balls
α' - α' = 60°- 45° = 15°.