(i) Mass of carbon in 3.38 g of CO2
= 3.38 g/44 x 12 = 0.922 g
Mass of hydrogen in 0.690 g of H2O
= 0.690 g/18 x 2 = 0.077 g
Total mass of the sample burnt = 0.922 g + 0.077 g = 0.999 g
Percentage of carbon in the fuel = {0.922}/{0.999 g} x 100 = 92.29%
Percentage of hydrogen in the fuel = {0.077 g}/{0.999 g} x 100 = 7.71%
Element |
Mass
Percent |
Atomic
mass |
Relative number
of atoms |
Simple
atomic ratio |
Carbon(C) |
92.29 |
12.0 |
92.29/12.0 = 7.69 |
7.69/7.69 = 1 |
Hydrogen(H) |
7.71 |
1.0 |
7.71/1.0 = 7.71 |
7.71/7.69 = 1 |
Therefore, empirical formula of the compound = CH
(ii) Volume of the gaseous fuel = 11.6 g
Molar mass of the fuel = {11.6 g}/{10.0 L} x 22.4 L/ml = 26.0 g mol-1
(iii) Empirical formula mass of the fuel = (12 + 1) g mol-1 = 13 g mol-1
Molar mass of the fuel = 26.0 g mol-1
n = {26.0 g mol-1}/{13 g mol-1} = 2
Molecular formula of the fuel = 2 x Empirical formula
= 2 x CH = C2H2