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The electron energy in hydrogen atom is given by En = {(-2.18 x 10-18)}/{n2} J. Calculate the energy required to remove an electron completely from the n = 2 orbit. What is the longest wavelength of light in cm that can be used to cause this transition?

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En = {-2.18 x 10-18}/{n2} J

Energy required to remove an electron from n = 2 is

ΔE = E - E2

Energy is related to the wavelength through the relationship

ΔE = hc/λ

or, λ = hc/ΔE

= {6.626 x 10-34 Js x 3 x 108 ms-1}/{5.42 x 10-19 J}

λ = 3.647 x 10-7 m

= 3.647 x 10-5 cm

Thus, the wavelength of the light that can be used to cause this transition is 3.647 x 10-5 cm (or 3647 Å)

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